Zinc oxide nanostructures enhanced photoluminescence by carbon

Scientific Reports volume 13, Article number: 9704 (2023) Cite this article 456 Accesses Metrics details ZnO/carbon-black heterostructures were synthesized using a sol–gel method and crystallized by

Scientific Reports volume 13, Article number: 9704 (2023) Cite this article

456 Accesses

Metrics details

ZnO/carbon-black heterostructures were synthesized using a sol–gel method and crystallized by annealing at 500 °C under 2 × 10−2 Torr for 10 min. The crystal structures and binding vibration modes were determined by XRD, HRTEM, and Raman spectrometry. Their surface morphologies were observed by FESEM. The Moiré pattern that is observed in the HRTEM images confirms that the carbon-black nanoparticles were covered by the ZnO crystals. Measurements of optical absorptance revealed that the optical band gap of the ZnO/carbon-black heterostructures increased from 2.33 to 2.98 eV as the carbon-black nanoparticle content increases from 0 to 8.33 × 10−3 mol owing to the Burstein–Moss effect. The photoluminescence intensities at the near-band edge and of the violet, and blue light were increased by factors about 68.3, 62.8, and 56.8, respectively, when the carbon-black contents is of the 2.03 × 10−3 mol. This work reveals that the proper carbon-black nanoparticle content involved increases the PL intensities of the ZnO crystals in the short wavelength regime, supporting their potential application in the light-emitting devices.

Zinc oxide is a promising material for use in the light-emitting devices1, photocatalysts2, gas sensors3, and solar cells4, owing to its n-type semiconducting property, wide band gap (3.3 eV)5, high exciton binding energy (60 meV)5, environmental friendliness6, low cost, and high physical and chemical stabilities7. Two methods that involve doping with elements Sb8, Ga9, Cu10, Gd11, and Li12, and heterostructures, such as RGO/ZnO2, Ag/ZnO6, ZnO/graphene13, Si/ZnO14, In2O3–ZnO15, and MoS2@ZnO16, can be used to modify and improve the emission of the light by ZnO. The most common means of synthesizing ZnO nanostructures include sol–gel6, thermal hydrothermal17, microwave hydrothermal18, thermally chemical vapor deposition (CVD)8, and the pulsed laser ablation (PLA)19 methods. As mentioned above, the sol–gel and thermal CVD approaches are the most popular, simple and efficient methods for synthesizing the ZnO nanostructures. Carbon-black has a similar crystal structure to that of graphite but it is tridimensional and less ordered. The carbon-layers in carbon-black are parallel to each other but exhibit low order, frequently as concentric layers with turbostratic structures20. Carbon-black has high conductivity, large specific surface area, stability21, and a low cost, and it is naturally abundant22. Therefore, it has potential uses in carbon fillers22, reinforcing and support materials for metal catalysts21, Li-ion batteries23, biomaterials24, fuel cells25, photocatalysts26, solar cells27, oxygen-reduction electrocatalysts28, and rubber compounds29.

Heterostructures, including metal/semiconductor, semiconductor/metal, and semiconductor/semiconductor heterostructures, are useful for modifying the photoluminescence properties of semiconductors, in a manner determined by the reconfiguration of the band structure between the connecting materials in a steady state. Wang et al. reported that V2O5@Pt nanostructures exhibited improved photoluminescent intensity at λ = 466 nm30; Wang et al. reported that RGO@ZnO nanostructures exhibited enhanced intensity at near band edge emission2; Rajas-Lopez et al. found that MoS2/hBN/SiO2 exhibited enhanced photoluminescent intensity at the emission energy of 1.85 eV31; Chi et al. revealed that NiFe/ZnO exhibited photoluminescence with increased intensity at λ = 414 nm32; and Kandhasamy et al. found that MoS2/graphene exhibited enhanced photoluminescence at λ = 690 nm and 430 nm33. Based on the aforementioned properties of carbon-black, the potential uses of ZnO, and the useful properties of heterostructures, a sol–gel method and the thermal CVD process were used herein to fabricate ZnO/carbon-black heterostructures, and the effects of the carbon-black nanoparticle content on the ZnO crystal structure and photoluminescent properties were systematically investigated. The sample names for ZnO/carbon-black heterostructures are denoted as ZC0, ZC1, ZC2, ZC3, and ZC4, corresponding to the addition of carbon-black contents of 0, 2.08, 4.16, 6.25, and 8.33 × 10−3 mol, respectively. CB25 and CB500 represent the carbon-black nanoparticles before and after annealing at 500 °C, respectively.

Figure 1a,b presents the XRD patterns of the carbon-black NPs before and after annealing at 500 °C, respectively. Both raw data curves include an intense peak at around 24.1°, and a weak peak at around 43.5°. Crystalline graphite yields a peak at around 26.56°34, which is larger than that at approximately 2.46° obtained in this work. This result reveals that the micro-crystallinity of the carbon-black NPs differs from that of the graphite34. The shift in the XRD diffraction angle has the following causes; (1) impurity doping, (2) lattice distortion, (3) lattice shrinkage, (4) compressive stress (shifts toward higher angles), and (5) tensile stress (shifts toward lower angles). The impurity doping is not considered herein. Therefore, the shift in the diffraction angle is caused by the mechanical deformation as a result of distortion and stressing. Therefore, the more intense peak at 24.1° corresponds to the (002) plane of the graphite34 while the weaker one at 43.5° represents the (111) plane of the diamond35. The graphite phase has a higher electrical conductivity than the diamond phase. The ratio of the proportions of the graphite and diamond phases in the carbon-black are estimated as:

and

respectively, where \(A_{graphite}\) and \(A_{diamond}\) are the integrated areas under the peaks of the graphite and diamond phases in the XRD patterns. The proportions of graphite (sp2-bonding) and diamond (sp3-bonding) in the carbon-black before thermal annealing at 500 °C are 87.2% and 12.8%, respectively, while those after annealing are 89.5% and 10.5%. These results confirm that the crystallinity of the graphite has been improved, so the thermal annealing improved the conductivity of the carbon-black. The peak of carbon (002) reveals that the carbon-black comprises the crystalline graphite phase and can be deconvoluted into the two peaks at around 19° and 24.4°. The former corresponds to the less-developed crystalline carbon (LDCC) phase and the latter corresponds to the more-developed crystalline carbon (MDCC) phase34. The respective intensity ratio IMDCC/ILDCC are 5.7 (Fig. 1a) and 6.7 (Fig. 1b), implying that the crystallinity of the carbon-black was improved by annealing at 500 °C, favoring enhanced conductivity. Figure 1c includes XRD peaks of ZC NSs but no carbon-related peaks are observed. The significant peaks at around 31.7°, 34.4°, 36.2°, 47.5°, and 56.5° correspond to the ZnO(100), ZnO(002), ZnO(101), ZnO(102), and ZnO(110) planes, based on the JCPDS 36-14516, confirming the typical ZnO hexagonal wurtzite structure. Table S1 presents the lattice constants, a (= b) and c, of ZnO and the c/a ratio. The lattice constants a and c, and the c/a ratio are around 0.325 and 0.52 nm, and 1.601, respectively. These results reveal that the carbon-black NPs have no effect on the crystal structure of the ZnO.

XRD patterns of carbon black treated at (a) 25 °C, (b) 500 °C, and (c) ZC NSs with various carbon-black contents.

The surface morphologies of the carbon-black NPs, ZC0, and ZC4 NSs are obtained by the FESEM, as shown in Fig. 2a–c, respectively. The ZC0 NSs, as shown in Fig. 2a, are cluster-like NSs. Figure 2b reveals that the pure carbon-black NPs have particle-like morphologies. ZC4 NSs form particle-like clusters, as shown in Fig. 2c, similar to those in of the pure carbon-black NPs in Fig. 2b. The sol–gel procedure, without any capping agents, is the primary method used in this work to synthesize the ZC nanostructures. As a result, the nanostructures in ZC0 exhibit larger sizes, as shown in Fig. 2a. The smaller sizes of ZC4 NSs, as shown in Fig. 2c, can be attributed to the ZnO covering on the surface of the carbon-black nanoparticles (particles size ~ 26 nm). Additionally, for the FESEM analysis, the samples were initially suspended in deionized water, then dropped onto the silicon wafer surface, and finally dried under ambient conditions. Consequently, the densities of the nanostructures vary, as observed in Fig. 2a–c. Figure S1a exhibits an FESEM image of the ZC4 NSs which is circled by the red-line. Figure S1b displays the FESEM-EDX spectrum and presents the corresponding values of Zn, C, and O in the inset. Figure S1c–e presents the individual elemental mappings of Zn, C, and O in the ZC4 NSs. The mapping confirms the presence of Zn, C, and O. Most of the elemental Zn, C, and O are detected inside the red circle, as shown in Fig. S1c–e.

FESEM images of (a) ZC0, (b) carbon black, and (c) ZC4 NSs.

Figure 3a,c, and b,d present low-magnitude and HR-TEM images of the pure carbon-black NPs following the annealing at 500 °C and of the ZC4 NSs, respectively. The d-spacing corresponding to the graphitic carbon (002) plane is 0.344 nm, as shown in Fig. 3c. The selected area diffraction (SAD) pattern of the carbon-black NPs, as shown in Fig. 3e, reveals its poly-crystalline structure with the graphitic carbon (002), (101), and (110) d-spacings of 0.345, 0.204, and 0.116 nm, respectively36. These results confirm that the carbon-black NPs are crystalline, consistent with the XRD patterns as well. The HRTEM image of the ZC4 NSs, shown in Fig. 3d, presents ZnO (100) plane with a d-spacing of 0.287 nm. The obtained d-spacing of 0.525 nm does not correspond to the phase of ZnO or carbon-black. The increased d-spacing is associated with the Moiré pattern, which arises from the interaction between the lattices of ZnO and carbon-black. The SAD pattern of the ZC4 NSs, as shown in Fig. 3f, reveals the crystalline structure of the ZnO with ZnO (100), ZnO (002), ZnO (102), and ZnO (103) planes. These results reveal that the synthesized crystalline ZnO covered the surfaces of the carbon-black NPs.

TEM images of (a) and (b), HRTEM images of (c) and (d), and SAD patterns of (e) and (f) of the carbon-black NPs and ZC4 NSs, respectively.

Figure 4a–d present the Raman spectra of the carbon-black NPs before and after the annealing at 500 °C, ZC0 and ZC4 NSs, respectively. The peaks at around 476 and 471 cm−1 in Fig. 4a,b are attributed to the disordered carbon-related bond (DCRB)37. Figure 4c shows the Raman spectrum of ZC0, which includes four characteristic peaks of the wurtzite ZnO at 326, 412, 435, and 577 cm−1, corresponding to the E2high–E2low, E1TO, E2high, and A1LO modes, respectively2. E2high is related to the oxygen in Zn–O in the wurtzite ZnO crystal structure38; A1LO is associated with oxygen deficiency in Zn–O39. A weak peak at 533 cm−1, shown in Fig. 4d, is attributable to the E1LO mode of wurtzite ZnO with the oxygen deficiency40. These results confirm that the hexagonal ZnO wurtzite structure has been established.

Raman spectra at the shorter Raman shifts of the (a) CB25, (b) CB500, (c) ZC0, and (d) ZC4 NSs.

Figure 5a–d, show mainly the D- and G-bands of the carbon-based materials. Figure 5a,b present the spectra of the pure carbon-black NPs before and after the annealing at 500 °C, respectively, and include three significant peaks. The peak at around 910 cm−1 is attributed to the disordered carbon-related bonds37; those at 1382 cm−1 and 1577 cm−1 correspond to the D- and G-bands of the carbon-base materials. The former is associated with disordered sp2 carbon atoms while the latter is associated with the graphite-like sp2 carbon atoms2. The intensity ratios between the G-band and D-band in CB25 and CB500 are 1.633 and 1.457, respectively, as depicted in Fig. 5a,b. These findings suggest that the carbon-black nanoparticles exhibit improved graphitic carbon structures after annealing at 500 °C, which is consistent with the XRD results. Figure 5c shows a peak at 1136 cm−1, which is characteristic of the multiphonon 2LO vibration mode of the wurtzite ZnO crystal41. Figure 5d presents three peaks of the ZC4 NSs at 1117, 1381, and 1582 cm−1, which are associated with the vibration modes of ZnO 2LO, and carbon-based D- and G-bands, respectively. These results confirm the formation of the wurtzite ZnO crystal and the presence of carbon-black material in the ZC4 NSs.

Raman spectra at the longer Raman shifts of the (a) CB25, (b) CB500, (c) ZC0, and (d) ZC4 NSs.

Figure 6 presents the absorptions by the ZC NSs, which were obtained using an integrating sphere. The absorption peak is located at the wavelength around 375‒400 nm, and the absorption by the ZC NSs is seven to ten times greater than that by the ZC0. The enhanced absorption by ZC NSs is attributable to the carbon-black NPs. Based on the absorption data, the optical band gaps of the ZC0, ZC1, ZC2, ZC3, and ZC4 NSs are estimated from the Tauc plot, as follows, and presented in Fig. S2a, S2b, S2c, S2d, and S2e, respectively.

where A is a constant; h is Planck’s constant; ν is the frequency of the incident light; n is the characteristic constant of the material, and Eg is the band-gap of the material. The constant n is 2 for a direct Eg material, such as ZnO, and 1/2 for indirect Eg materials42. The values of Eg for ZC0 and ZC4 NSs that are estimated from the Tauc plot are 2.33 and 2.98 eV, respectively. Figure S2f shows the variation of the Eg of ZC NSs with increasing carbon-black NP contents. The crystallinity of graphite-like carbon is improved by annealing at 500 °C. The concentrations of free electrons that are transferred from carbon-black NPs to ZnO nanostructures increases with the carbon-black content. Therefore, the increase in Eg is caused by the Burstein–Moss effect.

UV–visible absorption of the ZC NSs with various carbon-black NPs contents.

Figure 7a presents photoluminescence (PL) spectra of the pure carbon-black NPs and the ZC NSs. PL signals from the pure carbon-black NPs before and after annealing at 500 °C are not observed. The PL intensity of the ZnO, as shown in Fig. 7a, decreases at longer wavelengths (> 475 nm) as the carbon-black NP content increases. The PL intensity of the ZC NSs at shorter wavelengths (< 475 nm), as shown in Fig. 7a, increases with carbon-black NP content. Figure S3a–e present the deconvolutions of the PL spectra of the ZC0, ZC1, ZC2, ZC3, and ZC4 NSs, respectively, at short wavelengths (350‒475 nm). Three peaks are observed in such deconvoluted spectra. The peak at around 380 nm (E1, 3.26 eV) is attributable to the near band emission (NBE), which arises from the recombination of the electrons in the valence band (VB) of the ZnO and the holes in its conduction band (CB); the peak at 400 nm (E2, 3.1 eV) is associated with violet emission from the defect levels of the zinc interstitials \((Zn_{i}^{ \cdot \cdot } )\); the peak at 426‒440 nm (E3, 2.91‒2.81 eV) is attributable to transitions from the CB of the ZnO and the shallow donor-defect levels of \((Zn_{i}^{ \cdot \cdot } )\) to the acceptor defect levels of the zinc vacancies \((V_{Zn}^{{\prime\prime}} )\)2,43,44,45.

(a) PL spectra of ZC NSs with various carbon-black contents, (b) PL emission wavelengths and (c) PL intensities of ZC NSs with various carbon-black contents in the region of shorter wavelengths.

Figure 7b shows that the wavelengths of PL emissions at E1 and E2 are not significantly shifted, while that at E3 is clearly blue-shifted. Figure S2f reveals that the optical band gaps of the ZC NSs increase with the carbon-black NP content, as a result of the Burstein–Moss effect. These results reveal that the electrons from the carbon-black NPs migrate mostly to the defect levels of the \((Zn_{i}^{ \cdot \cdot } )\). Figure 7c presents the PL intensities of the ZC NSs at E1, E2, and E3, respectively. The intensities of PL from ZC NSs at E1, E2, and E3 are enhanced by factors of 68.3, 62.8, and 56.8, respectively, when the carbon-black NP content is of the 2.03 × 10−3 mol. The PL intensity decreases as the carbon-back NP content is increased from 2.03 × 10−3 to 8.33 × 10−3 mol. Table S2 presents the PL intensities of the ZC NSs at short wavelengths and the relevant enhancement factors. The broad emission band at longer wavelengths (> 475 nm) is observed in Fig. 7a, and is identified with deep level emission (DLE). DLE arises from the defect levels within the band gap of the ZnO, such as oxygen vacancies \((V_{O}^{ \cdot \cdot } )\), zinc vacancies \((V_{Zn}^{{\prime\prime}} )\), zinc interstitials \((Zn_{i}^{ \cdot \cdot } )\), and oxygen antisites \((O_{Zn}^{\prime\prime\prime\prime} )\)8. The defect levels of \((V_{O}^{ \cdot \cdot } )\) are primarily responsible for the DLE46. These results confirm that the proper carbon-black NP content incorporated increases PL intensity of ZnO in the short-wavelength region, and significantly reduces DLE. The related works on the photoluminescence properties of heterostructures comprising ZnO nanostructures and various carbon-related nanomaterials, such as reduced graphene oxides (RGO), carbon quantum dots (QDs), graphene, multiwall carbon nanotubes (MWCNTs), and carbon nanomaterials, are listed in Table S3. These studies indicate that the presence of carbon-related materials has an impact on the photoluminescence properties when integrated with ZnO nanostructures. Under appropriate conditions, the PL intensities of ZnO nanostructures can be enhanced through the incorporation of carbon-related materials.

Figure 8a shows a proposed band diagram of the ZC1 NSs at short wavelength region. The electrons in the VB of the ZnO are excited to the CB by the incident light (EI). Some of these excited electrons should transfer to the lower defect level of \((Zn_{i}^{ \cdot \cdot } )\). In addition, the free electrons in the carbon-black NPs migrate to the CB of the ZnO and the shallow donor level of \((Zn_{i}^{ \cdot \cdot } )\) as a result of the improved conductivity of the carbon-black NPs and the enhanced electron transfer between ZnO and carbon-black NPs. Therefore, the emission intensities for ZC1 are increased2,6. Apart from the free electrons are form the CB of the ZnO to the \((Zn_{i}^{ \cdot \cdot } )\) defect level, the variations in the estimated optical band gap of the ZC NSs (Fig. S2f) show that the free electrons migrate mostly to the \((Zn_{i}^{ \cdot \cdot } )\) so the E2 emission is more intense than the E1 and E3 emissions. The PL intensities at shorter wavelength decrease as the carbon-black NPs content increases, as shown in Fig. 7a, which can be attributed to the following reasons. (a) the re-migration of the electrons from ZnO to the carbon-black NPs; (b) the high conducting carbon-black nanoparticles act as the carrier trapping sites, implying the increment of the free carriers trapping sites leading to the decreasing PL intensities. Figure 8b presents a proposed band diagram of the ZC4 NSs at longer wavelengths. The incident light (EI) excites the electrons from the VB of the ZnO to the CB. These excited electrons should transfer to the lower defect level of \((V_{O}^{ \cdot \cdot } )\) and migrate to carbon-black nanoparticles acting as the electron traps. The free electrons at the CB and the defect donor levels of \((V_{O}^{ \cdot \cdot } )\) migrate to the carbon-black NPs from the interface with ZnO as a result of the improved conduction of the carbon-black NPs. Therefore, the electrons migrate from the CB and \((V_{O}^{ \cdot \cdot } )\) defect level in the ZnO to the carbon-black nanoparticles leading to the decreasing DLE intensity by the ZC NSs2,6.

The proposed band diagrams of (a) ZC1 NSs at shorter and (b) ZC4 NSs at longer wavelength regions.

The ZnO/carbon-black nanostructures were synthesized using the sol–gel method, and crystallized by annealing at 500 °C and 2 × 10−2 Torr. The crystal structures and bonding-vibration modes were systematically investigated and analyzed using the XRD, HRTEM, and Raman spectrometry. The Moiré patterns observed in the HRTEM images confirm that the carbon-black nanoparticles were covered by the ZnO crystals. The optical absorptance revealed that the band gap of the ZnO/carbon-black nanostructures increases with the carbon-black content owing to the Burstein–Moss effect. The photoluminescence spectra revealed that the emission intensities of the ZnO crystals at the near-band edge and in the violet and blue-light regions were enhanced by factors of 68.3, 62.8, and 56.8, respectively, when the carbon-black content was 2.03 × 10−3 mol. The proper carbon-black nanoparticle content increases the intensity of the luminescence of the ZnO crystals in the short-wavelength regime. The ZnO/carbon-black nanostructures have promises for use in the light-emitting devices.

ZnO and the ZnO/carbon-black nanostructures (NSs) were fabricated using the sol–gel process from the precursor material zinc nitrate hexahydrate (Zn(NO3)2·6H2O, Choneye) that was mixed with carbon-black nanoparticles in DI water. A 0.28 M solution of Zn(NO3)2·6H2O in DI water was stirred for 60 min to ensure homogeneity. Then, highly conductive carbon-black nanoparticles with a size of 26 nm (NPs, Hondwen Co., Ltd.) were separately added in amounts of 0, 2.08, 4.16, 6.25, and 8.33 × 10−3 mol to the Zn-based solutions, which were stirred for 60 min. The aqueous mixtures thus obtained were baked in an oven for 30 h at 1 atm and 180 °C to remove moisture and yield dry mixed powder. Subsequently, the dried powder was put in a horizontal quartz-tube furnace and heated to 500 °C (10 °C/min), which was held for 10 min for crystallization at a pressure of 2 × 10−2 Torr. The final products were collected at room temperature (RT) and those with carbon-black contents of 0, 2.08, 4.16, 6.25, and 8.33 × 10−3 mol were denoted as ZC0, ZC1, ZC2, ZC3, and ZC4, respectively. The carbon-black nanoparticles before and after annealing at 500 °C are denoted as CB25 and CB500, respectively. Table 1 presents the precursor contents of zinc nitrate hexahydrate (Zn(NO3)2·6H2O) and carbon-black nanoparticles, as well as the annealing treatment of the samples.

The crystal structures of ZC NSs were determined using a high-resolution transmission electron microscope (HRTEM; JEOL JEM-2010) and an X-ray diffractometer (XRD, Bruker D2 PHASER) with CuKα radiation with λ = 1.5405 Å at 40 kV and 30 mA. Surface morphologies of ZC NSs were observed by the field emission scanning electron microscopy (FESEM; JOEL JSM-6335F). The bonding vibration modes of ZC NSs were analyzed by the Raman spectroscopy (3D Nanometer-scale Raman PL microspectrometer, Tokyo Instruments, INC.) with a semiconductor laser with an excitation wavelength of 488 nm. The absorption spectra of the ZC NSs in the UV–visible range were obtained using a UV–visible spectrophotometer (Cary 50, Varian). The photoluminescence (PL) spectra were obtained using a room-temperature confocal Raman spectrometer (Alpha 300, Witec, Germany) with a 266 nm semiconducting laser as the excitation source.

The datasets used and/or analysed during the current study available from the corresponding author on reasonable request.

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The authors would like to thank the Ministry of Science and Technology of the Republic of China, Taiwan, for financially supporting this research under contract MOST 110-2221-E-034-006.

These authors contributed equally: Chih-Chiang Wang and An-Ya Lo.

Department of Chemical and Materials Engineering, National Chin-Yi University of Technology, Taichung, 411030, Taiwan

Chih-Chiang Wang & An-Ya Lo

Department of Materials Science and Engineering, National Chung Hsing University, Taichung, 40227, Taiwan

Ming-Che Cheng, Yu-Sung Chang, Han-Chang Shih & Fuh-Sheng Shieu

Department of Chemical Engineering and Materials Science, Chinese Culture University, Taipei, 11114, Taiwan

Han-Chang Shih

Instrument Center, The Office of Research and Development, National Chung Hsing University, Taichung, 40227, Taiwan

He-Ting Tsai

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Conceptualization, H.C.S. and F.S.S.; methodology, H.C.S., F.S.S., A.Y.L., and C.C.W.; software, C.C.W., M.C.C., and Y.S.C.; validation, C.C.W., A.Y.L., M.C.C., and Y.S.C.; formal analysis, C.C.W., A.Y.L., and H.T.T.; investigation, C.C.W., A.Y.L., M.C.C., and Y.S.C.; resources, H.C.S. and F.S.S.; data curation, C.C.W., M.C.C., and Y.S.C.; writing—original draft preparation, C.C.W.; writing—review and editing, H.C.S., F.S.S., and A.Y.L.; visualization, C.C.W., A.Y.L., M.C.C., and Y.S.C.; supervision, H.C.S. and F.S.S.; project administration, H.C.S.; funding acquisition, H.C.S. All authors have read and agreed to the published version of the manuscript.

Correspondence to Chih-Chiang Wang or Han-Chang Shih.

The authors declare no competing interests.

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Wang, CC., Lo, AY., Cheng, MC. et al. Zinc oxide nanostructures enhanced photoluminescence by carbon-black nanoparticles in Moiré heterostructures. Sci Rep 13, 9704 (2023). https://doi.org/10.1038/s41598-023-36847-1

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Received: 13 April 2023

Accepted: 11 June 2023

Published: 15 June 2023

DOI: https://doi.org/10.1038/s41598-023-36847-1

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Zinc oxide nanostructures enhanced photoluminescence by carbon